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Category: News

Walmart Foundation grant aimed at reducing plastic waste

potato chips bag on White background

An $800,000 grant from the Walmart Foundation to the University of Georgia New Materials Institute will help researchers understand how multilayer plastic packaging biodegrades and also help manufacturers in their attempts to design and select more sustainable materials. The research funded by the grant will seek to yield both upstream and downstream solutions aimed at reducing the buildup of plastic packaging in the environment.

“The grant will help us examine how the selection of materials for flexible packaging influences the biodegradability of that plastic in different environments, and also how the unique microbes that exist in these environments influence the biodegradation process,” said Jason Locklin, director of the New Materials Institute and a principal investigator on the grant. “Our data will be used to propose new and logical standards to help find ways to manage packaging waste that is presently being thrown away or blown away.”

Multilayer packaging protects nearly half of the food produced from spoiling before it can be eaten. This complex packaging is also extremely difficult material to recover and recycle, said Locklin. Currently, when two or more types of plastic are bound together to create this flexible packaging, the composite film either does not biodegrade or it biodegrades at a rate too slow to meet certification requirements that allow the manufacturer to claim its film will biodegrade; these requirements vary by country.

There are numerous microbial environments in which plastic packaging—when comprised of the right materials—could fully biodegrade, including landfills, municipal waste water treatment plants and industrial composting facilities. The research team will examine packaging biodegradability in all of these settings and propose new testing standards that governments and certification laboratories can adopt so that all flexible plastic packaging is subjected to rigorous, standard testing protocols.

The team will also conduct a nationwide assessment of existing waste management infrastructure to determine the most advantageous means of managing waste, including the proximity of composting, recycling and other waste processing facilities to the communities they serve. As part of this assessment, the team will also consider whether additional infrastructure may be needed as new types of materials produced to replace conventional plastics begin to make their way into these waste and recycling streams.

The other principal investigators on the project are Jenna Jambeck, who leads the institute’s Center for Circular Materials Management, and Evan White, an assistant research scientist. Jambeck is an associate professor in the College of Engineering. Locklin is a professor of chemistry and biochemical engineering who is jointly appointed to the Franklin College of Arts and Sciences department of chemistryand the College of Engineering.

“Tackling our plastics problem is going to require new approaches to the entire cycle of production, consumer use and disposal,” said David Lee, vice president for research at UGA. “We’re grateful to the Walmart Foundation for its support of research that aims to create benefits both for the environment and for the communities it serves.”

The UGA New Materials Institute is committed to preventing waste through the design of materials and systems that adhere to Green Engineering principles. The institute partners with industry and businesses to design materials for their use that are bio-based, fully biodegradable, or completely recyclable, and safe for people, animals and our planet. In addition, it works with businesses, governments, foundations and other organizations to redesign systems so that they generate less waste and promote circularity in materials management. The New Materials Institute is also shaping the future by training the next generation of scientists and engineers on the importance of considering Green Engineering design principles in everything they do. For more information, visit www.newmaterials.uga.edu.

Lecture Series: How sustainable polymers can shape the future of plastics

Marc Hillmyer, director of the Center for Sustainable Polymers at the University of Minnesota and senior editor of Macromolecules, will present a lecture titled, “How sustainable polymers can shape the future of plastics,” on March 1, 2019.

The lecture will be held at 12:30 p.m. in the Coverdell Center Auditorium, room 175.

Click on the link below to download a flyer on Dr. Hillmyer’s lecture.

PHA development project featured in PRISM

Jason Locklin, director of the UGA New Materials Institute, recently talked to PRISM, the American Society for Engineering Education’s magazine, about the advantages and challenges of working with PHA, and how PHA can displace conventional plastics currently used in single-use packaging.

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Royal statistic of 2018: 90.5% of plastic not recycled

Jenna Jambeck

A finding from University of Georgia research has been named the 2018 International Statistic of the Year by the Royal Statistical Society. CNN International interviewed the College of Engineering’s Jenna Jambeck, who worked with colleagues at the University of California, Santa Barbara, and the Sea Education Association on the groundbreaking research.

More than 90 percent of plastic has never been recycled, according to the research. Prior to the research, it was unclear exactly how much plastic was ending up in landfills or, even more problematic, in oceans and forests around the world. The new statistic lends a sense of scale to the problem of global plastic pollution.

“This statistic illustrates that many of the characteristics of plastic that make it so useful — it’s light-weight, can be any color and shape with additives — also can reduce its value at its end of life and make it difficult to manage in the waste stream,” Jambeck said. “It often ends up unrecycled or mismanaged and ends up in our ocean. Besides reduction where appropriate, we need to design products and materials proactively to work within our waste and materials management systems.”

Jambeck’s previous work includes a 2015 study that was the first to estimate how much of the plastic waste produced on land made its way into the world’s waterways. Her follow-up two years later determined the amount of plastic produced worldwide since large-scale production of the synthetic materials began in the early 1950s.

Her research in 2018 also illustrated that half of the plastic meant for recycling from around the globe was being exported to China, until China ended this practice—creating even more challenges for the global recycling industry.

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A video is online at https://www.cnn.com/videos/tv/2018/12/19/exp-statistic-of-the-year-on-plastic-waste.cnn

For more information about Jenna Jambeck and her work, visit https://greatcommitments.uga.edu/story/turning-trash-into-treasure/

 

UGA New Materials Institute joins NSF-funded Center for Bioplastics and Biocomposites

Locklin at CB2 planning meeting
Jason Locklin, director of the UGA New Materials Institute, addresses attendees at the CB2 planning meeting held on the UGA campus in early 2018.

Athens, Ga.­­ – The University of Georgia New Materials Institute has been awarded a grant as the third site for the National Science Foundation’s Center for Bioplastics and Biocomposites, or CB2, an Industry/University Cooperative Research Center.

UGA was selected, in part, on the strength of 10 project proposals that were presented at a site planning meeting held earlier this year. As a CB2 site, the New Materials Institute will contribute additional capabilities in the areas of new biodegradable polymers and additives; advanced fibers; durable coatings and finishes, including foams; nonwoven fibers; and novel thermoplastics with excellent barrier properties for films, sheet goods and filtration media.

“The field of new and sustainable materials has quickly become one of the University of Georgia’s research strengths as we look for innovative ways to leave a healthier planet for future generations,” said David Lee, UGA vice president for research. “This CB2 award fits with our strategy of developing effective partnerships with colleagues in both academia and industry to move this critical field forward, and I’m excited about the new opportunities for research collaborations that this partnership will bring.”

A complementary focus

Iowa State University’s Biopolymers & Biocomposites Research Team and Washington State University’s Composite Materials and Engineering Center—the two founding members of CB2—have strong programs in sustainability, bioproducts and bioplastics. The New Materials Institute’s complementary focus on biodegradable alternatives for packaging will broaden CB2’s range of offerings to its industry partners, which currently include Ford, Hyundai, John Deere, 3M, Myriant and ADM.

“The addition of UGA to CB2 opens many new research areas, and engages new and fast growing industry sectors that are focused on sustainable packaging,” said David Grewell, founder and director of CB2, and chair of the Department of Industrial and Manufacturing Engineering at North Dakota State University. “I expect to see an accelerated growth of research, impact on industry, and student outcomes.”

Global plastic production reached 299 million metric tons in 2014. About 40 percent of all plastics manufactured annually are used in packaging, which is immediately discarded after use. An estimated 5 to 12 MMTs of mismanaged plastic waste reaches the oceans annually, but this is expected to rise to as much as 17 MMTs annually by 2025 due to increasing population, plastic consumption and waste generation.

More opportunities for students

“In addition to boosting our opportunities for collaborative research, we will increase experiential learning opportunities for our students,” said Jason Locklin, director of the New Materials Institute, and a professor of chemistry and biochemical engineering who is jointly appointed to the Department of Chemistry and the College of Engineering. “Through CB2, they will have more exposure to cutting-edge research as well as outreach opportunities that will enable them to enter the workforce immediately, with the ability to contribute and have positive impact.”

The UGA New Materials Institute is committed to preventing waste through the design of materials and systems that adhere to green engineering principles. The Institute partners with industry and businesses to design materials for their use that are bio-based, fully biodegradable, or completely recyclable and safe for people, animals and our planet. In addition, it works with businesses, governments, foundations and other organizations to redesign systems so that they generate less waste and promote circularity in materials management. The New Materials Institute is also shaping the future by training the next generation of scientists and engineers on the importance of considering green engineering design principles in everything they do.

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Writer/Contact: Kat Yancey Gilmore, 706/542-6316, kygilmor@uga.edu.

Micronizing ocean plastics threaten sea turtle populations, ocean life cycle

This loggerhead post-hatchling was rehabilitated and released by the Loggerhead Marinelife Center. The vial contains plastic that was excreted by the sea turtle during its stay at LMC in 2017. Photo provided by Loggerhead Marinelife Center.

Ingestion of degrading ocean plastics likely poses a substantial risk to the survival of post-hatchling sea turtles because the particles can lead to blockages and nutritional deficiencies, according to new research from Loggerhead Marinelife Center and the University of Georgia. This puts the survival of all sea turtle populations at risk, because sea turtles may take decades to become sexually mature. The study also suggests that micronizing plastics could have tremendous negative implications for the ocean’s food web.

“We may be in the early phases of the first micronized plastic waste-associated species population decline or extinction event,” said co-author Branson W. Ritchie, a veterinarian with more than 30 years of experience in exotic and wildlife medicine and the director of technology development and implementation for the UGA New Materials Institute. “But, an even bigger issue is what micronizing plastics are doing to the ocean’s ecosystem. As ocean plastics continue to micronize, smaller and smaller particles are being consumed by the smallest creatures in our oceans, which compromises the entire food chain, because the plastic in these animals inhibits their ability to uptake the nutrients they need to survive. If the level of mortality we have observed in post-hatchling sea turtles also occurs for zoo plankton, baby fish and crustaceans, then we will witness a complete disruption in our ocean life cycle.”

The researchers collected 96 post-hatchling sea turtles that had washed back onto the beaches along a stretch of Florida’s coastline between Vero Beach and Lake Worth. The area is just south of the Archie Carr National Wildlife Refuge, named for the researcher who spurred the sea turtle conservation movement, and is part of the largest rookery in the United States for loggerhead and green turtles. More than 90 percent of the U.S. loggerhead population nests in Florida, said study co-author Charles Manire, a veterinarian who is director of research and rehabilitation for Loggerhead Marinelife Center.

Nearly half of the 96 recovered turtles were rehabilitated by LMC and released back into the ocean. During their time in rehabilitation, all passed some amount of plastic, said licensed veterinary technician Samantha Clark, a co-author who cared for the turtles at LMC. The remainder of the collected turtles died and 27 of these were examined for the study. Ninety-three percent had some amount of ingested plastic particles in them, leading the team to theorize that many died due to blockages or nutritional deficiencies associated with plastic ingestion.

“Sea turtles are known to mistake ocean plastics for prey, like crab or fish eggs, or in the case of larger sea turtles, floating plastic bags for jellyfish,” Clark said.

“Our findings suggest that far fewer post-hatchlings may be surviving long enough to reproduce. This has devastating implications for the seven species of sea turtles struggling to survive,” said Manire. “If other sea turtle populations are experiencing similar mortality rates, we predict that there will be insufficient numbers of sea turtle hatchlings reaching sexual maturity to offset natural and other human-associated losses.”

Historically, researchers have estimated that only one in 1,000 survives long enough to fully mature, but some recent estimates have suggested that number may be one in 10,000.

As plastic waste has accumulated in the marine environment, there has been an increase in the reports describing ingestion of plastics by sea turtles. Plastic is now the most common form of marine debris. Globally, at least 690 marine species, including sea turtles, seabirds, seals, sea lions, whales, fish and invertebrates, have reportedly become ill or died following entanglement in or ingestion of marine plastics.

The study team made another remarkable discovery: Once ingested, the plastic particles may continue to deteriorate to a size so small that it has never been documented or described previously for ingested particles. Using Raman spectroscopy and atomic force microscopy, the team characterized both the types of plastics and the sizes of the particles they found.

“We found particles ranging from millimeter-sized fragments to nanoparticles that measured on average 52 nanometers, and the smallest fragments we found measured 5 nanometers,” said Jason Locklin, director of the UGA New Materials Institute and a co-author on the study. “The smaller these particles are, the more unstable they become.”

“Of these larger mesoparticles, 54.1 percent of what we found were polyethylene and 23.7 percent were polypropylene,” said lead author Evan White, an assistant research scientist at the New Materials Institute who analyzed the particles. “Polyethylene is the most common plastic and is primarily used for packaging, especially food packaging. Polypropylene is the second most-commonly produced plastic and has a wide variety of uses, including food packaging.”

For examples of scale, microparticles include pollen, flour or powdered sugar. A nanometer is one-billionth of a meter; a human hair is about 80,000 to 100,000 nanometers wide.

The study was funded in part by the RWDC Environmental Stewardship Foundation, which has partnered with the UGA New Materials Institute to research and develop bio-based, fully biodegradable plastics.

The study team also included Shunli Wang, of the New Materials Institute, and UGA undergraduate Benjamin Crawford. The study, titled “Ingested Micronizing Plastic Particle Compositions and Size Distributions within Stranded Post-Hatchling Sea Turtles,”was published in Environmental Science and Technology.

UGA to test first fully biodegradable plastic straw

This PHA resin is bio-based and fully biodegradable. The formula will be used to create a prototype for the world’s first fully biodegradable plastic straw. Photo by UGA/Dorothy Kozlowski.

A research team that includes partners from the University of Georgia New Materials Institute and the RWDC Environmental Stewardship Foundation will develop a fully biodegradable plastic straw thanks to an award from Singapore’s Temasek Foundation Ecosperity.

The $719,000 award represents the top prize in Ecosperity’s inaugural Liveability Challenge and was presented to RWDC Industries in July in Singapore. UGA researchers, graduate students and a UGA alumnus, working with RWDC Foundation funding, synthesized a food contact polymer that they will now attempt to develop into a commercially viable straw, which RWDC would then bring to market.

The next step is for RWDC and the New Materials Institute to create prototypes. Then they must prove the straws can be manufactured consistently, produced at a scale to meet global demand and are fully biodegradable in soil, fresh water and marine water. Testing largely will be conducted in a New Materials Institute laboratory built with RWDC grant funding.

Few non-plastic alternatives

Currently, there are few non-plastic straw alternatives available to consumers. Many plastics branded as “biodegradable” are made from plant-based material called polylactic acid, or PLA. PLA-based plastics are compostable in limited environments, but they do not fully degrade outside of these settings.

“Plastics made from PLA only degrade in industrial compostable settings under high temperature and humidity conditions,” said Jason Locklin, director of the New Materials Institute and a professor in the Franklin College of Arts and Sciences department of chemistry, and the College of Engineering, who worked on the project. “Other types of plastic, which are petroleum-based, last forever. Less than 10 percent of these plastics are recycled. The 90 percent that aren’t recycled will ultimately fragment over time, and as micronized plastic, can end up in our soil, rivers and oceans—forever.”

The team’s biodegradable straws are based on a proprietary, bio-based resin in the class of polymers called polyhydroxyalkanoates, or PHAs.

Effective environmentally friendly straws

For the PHA-straw to be a viable product in the marketplace, it will have to perform as well as the plastic straws currently in use. It must also be cost-effective over its entire life cycle, including disposal, said Branson Ritchie, director of technology development and implementation for the New Materials Institute, and a distinguished research professor at UGA.

“The PHA-straw is an initial step toward our shared goal, with RWDC, of replacing single-use, petroleum-based plastics with plastics made from our biodegradable resins,” Ritchie said. “We can tweak our formulas and expand our technology on a product-by-product basis. This keeps a manufacturer’s costs down because they don’t have to reinvent their processes, and this facilitates their ability to quickly produce environmentally-friendly plastic products.”

Partnership

RWDC provided a substantial grant in order to quickly boost the New Materials Institute’s capabilities and position it for fast-tracking development, testing and illustration of the scalability necessary to create products from the bio-based resins we have co-developed, said Daniel Carraway, a scientist, inventor and entrepreneur who co-leads RWDC Industries and its foundation. Carraway earned his doctorate in forest biotechnology from UGA in 1996.

PHA resin inventors
From left: Branson W. Ritchie, Daniel Carraway and Jason Locklin. Photo by Terry Allen.

“We have positioned the New Materials Institute to succeed in the critical step of translating these technologies beyond the laboratory scale,” Carraway said. “This straw will be the first of our fruits from these endeavors and the first product from what we view as a long-term partnership.”

The UGA New Materials Institute is committed to preventing waste through the design of materials and systems that adhere to Green Engineering principles. The Institute partners with industry and businesses to design materials for their use that are bio-based, fully biodegradable, or completely recyclable, and safe for people, animals and our planet. In addition, it works with businesses, governments, foundations and other organizations to redesign systems so that they generate less waste and promote circularity in materials management. The New Materials Institute is also shaping the future by training the next generation of scientists and engineers on the importance of considering Green Engineering design principles in everything they do.

A novel ‘smart’ approach to metabolic engineering

Yajun Yan is an associate professor in the UGA College of Engineering and the New Materials Institute.

Inspired by natural processes, UGA researchers used a genetic toolkit to build a metabolic sensor and control network that works in real time to regulate a cell’s production of a certain biochemical. Specifically, the researchers reprogrammed the regulatory network of E. coli to increase the bacteria’s production of muconic acid, a potential precursor in the production of nylon 66, which is commonly used in textiles and plastics.

The team included Yajun Yan, an associate professor in the College of Engineering and the New Materials Institute, and co-first authors Yaping Yang, a postdoctoral research assistant in Yan’s laboratory, and Yuheng Lin, the chief technology officer of BiotecEra, Inc. Lin and Yan are co-founders of the biotechnology company housed in UGA’s Innovation Gateway Incubator. Their study was published in Nature Communications.

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Recycling in U.S. is becoming more expensive, due to China and ‘dirty’ recycling

The global waste management market is shifting and the change is beginning to negatively impact the recycling industry in the United States. In Maine, a town in Hancock County plans to stop curbside recycling on Sept. 1, following a steep rise in the costs associated with the program. While some of the rising costs are associated with China’s ban on 24 waste items from the U.S. and other countries, some costs are due to so-called “dirty” recycling practices by consumers: items in the recycling stream that either cannot be recycled or are too expensive to clean and resell for profit.

Amy Brooks, a doctoral student in the New Materials Institute who co-authored a recent study on China’s ban of plastic imports, says that waste managers will have to seek new markets and solutions that can help mitigate the rising costs of recycling.

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Study: PHA is an eco-friendly alternative to petrochemical plastics

A recent study from the UGA New Materials Institute found that polyhydroxyalkanoate (PHA) material is an eco-friendly alternative to petrochemical plastics and effectively biodegrades in aerobic or anaerobic environments, such as a landfill, waste treatment facility or the ocean. The researchers examined PHA material developed by Danimer Scientific, which develops and manufactures biodegradable plastic products.

To determine how PHA biodegrades in a proper waste management scenario, researchers measured the gaseous carbon loss of PHA samples placed in anaerobic sludge after 40 – 60 days of incubation and compared the levels to those of cellulose powder in the same setting. The anaerobic degradation of PHA was not significantly different from that of the cellulose powder. In addition, the methane yields of PHA were found to be similar to food waste, which suggests the material could be effectively processed alongside common organic waste in a landfill.

The study, “Biodegradation of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Plastic under Anaerobic Sludge and Aerobic Seawater Conditions: Gas Evolution and Microbial Diversity,” was published in Environmental Science and Technology.

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